Achieving the Enhanced Photocatalytic Degradation of Ceftriaxone Sodium Using CdS-g-C3N4 Nanocomposite under Visible Light Irradiation: RSM Modeling and Optimization
نویسندگان
چکیده
In this research, the cadmium sulfide—graphite carbon nitride (CdS-g-C3N4) nanocomposite was synthesized and characterized by X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), energy-dispersive spectrometer (EDX), transmission (TEM) techniques. The photocatalytic activity of as-prepared evaluated in degradation ceftriaxone sodium (CTX) antibiotic from aqueous solution under visible light irradiation. influence operational variables such as amount photocatalyst (g/L), initial CTX concentration (mg/L), pH, irradiation time (min) on photodegradation process investigated optimized using response surface methodology (RSM)—central composite design (CCD) model. maximum percentage (92.55%) obtained optimal condition, including 0.06 g/L CdS-g-C3N4 photocatalyst, 15 mg/L CTX, pH = 10.5, 81 min. efficient performance is due to appropriate alignment energy levels between CdS g-C3N4, which synergistically impact charge separation efficiency CTX. kinetics well described Langmuir–Hinshelwood’s pseudo-first-order model (kapp 0.0336 min−1).
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ژورنال
عنوان ژورنال: Journal of Inorganic and Organometallic Polymers and Materials
سال: 2021
ISSN: ['1574-1451', '1574-1443']
DOI: https://doi.org/10.1007/s10904-021-01967-6